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Methyl benzoate

Benzoic acid methyl ester

Benzenoid ester · C₈H₈O₂

Chemical structure of Methyl benzoate
2D structure PubChem / NCI CIR

Chemical info

CAS number CAS
93-58-3
Molecular formula
C₈H₈O₂
Molecular weight
136.15 g/mol
Aroma
Sweet floral, faintly ylang, warm. A floral base note in tuberose and jonquil.

Safety

Low concern · Safe at standard use

Methyl benzoate is a common aromatic ester in floral essential oils. Available data indicate minimal risk.

Skin. A 4 percent test on volunteers caused no sensitization. The compound is non-phototoxic.

Acute toxicity. Acute oral LD50 is 1.35 to 3.5 g/kg in rats, 3.0 to 3.33 g/kg in mice, 4.1 g/kg in guinea pigs, 2.17 g/kg in rabbits.

Mutagenicity. Non-mutagenic in the Ames test.


Usage guidelines

Concern level
Low
Regulatory limit
No IFRA or EU limit set specifically

Found in essential oils

Principal sources
Jonquil23.4 %
Tuberose7.8 %
Ginger lily5.7 %
Ylang-ylang0.2 – 5.6 %
Champaca (orange)1.0 – 5.0 %
Bakul3.8 %
Jasmine sambac2.6 %
Jasmine0.2 – 1.0 %

Notes

Methyl benzoate is one of the simplest aromatic esters in perfumery. It serves as an intermediate in the synthesis of many other fragrance compounds.