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Clary sage absolute / concrete

Xô thơm clary absolute và concrete

Salvia sclarea

Clary sage concrete, Sclareol-rich extract, Sauge sclarée absolue

Lamiaceae · Ngọn hoa (đài hoa và lá) · Flowering tops (calyces and leaves) · Solvent-extracted (concrete, absolute), often from distillation residue


Aroma

Warm herb, dry tea, tobacco, amber, a hint of leather. Little of the oil's fresh green top; a balsamic, near-amber drydown.


Safety

Sclareol, the main constituent of the concrete and absolute, is under an IFRA specification standard (2005). Clary sage absolute has no other dedicated standard in the IFRA 51 index.

Linalool and linalyl acetate are present; linalool is an EU-labelled allergen above threshold. The library's clary sage oil page records a higher sensitisation profile for the absolute than for the oil. Store dark, sealed and cool.


Usage guidelines

Note
Base
Form
Concrete, absolute, purified sclareol
Role
Herbal amber base; sclareol source
Industrial use
Feedstock for ambroxide
Storage
Dark, sealed, cool
Harvest
6, 7, 8

Chemistry

Key constituents
Sclareolmajor
Linalyl acetatepresent
Linaloolpresent
Germacrene Dminor

Origins

France · Bulgaria · China


Notes

Salvia sclarea is a Mediterranean biennial grown on a large scale in France, Bulgaria, Russia, Ukraine and China. It flowers in its second summer; flowering tops are cut at full bloom.

Sclareol is a diterpene diol concentrated in the calyces. Being practically non-volatile, it is scarce in the distilled oil. The distillation residue or dried tops are solvent-extracted to obtain a sclareol-rich concrete.

An absolute is made in two steps. The raw material is extracted with a non-polar solvent such as hexane to give a waxy concrete. The concrete is then washed with ethanol, chilled to precipitate waxes, filtered and freed of alcohol. What remains is the absolute.

Sclareol is the main feedstock for synthesising ambroxide, the replacement for ambergris. Much of the world's clary sage is grown for this purpose rather than for oil. Purified sclareol is also sold as a material in its own right.

In perfumery clary sage absolute gives an amber, tobacco and warm-herb base. It links lavender, labdanum, woods and leather. It is clearly different from the oil, which is fresh, green and rich in linalyl acetate.

The IFRA standard for sclareol is a specification standard: it sets quality requirements on the material rather than a concentration limit per product category.


Sources

  1. IFRA Standards, 51st Amendment: Index of IFRA Standards (notified 30 June 2023)
  2. Commission Regulation (EU) 2023/1545 amending Reg. 1223/2009 on labelling of fragrance allergens
  3. PubChem compound record: Sclareol
  4. Tisserand R., Young R. Essential Oil Safety, 2nd ed., Churchill Livingstone 2014
  5. Schalk M. et al. Toward a biosynthetic route to sclareol and amber odorants. J. Am. Chem. Soc. 134 (2012) 18900–18903
  6. The Good Scents Company Information System, material entries