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Ambergris

Long diên hương (ambergris)

Physeter macrocephalus (nguồn gốc)

Ambergris tincture, Ambre gris, Grey amber

Physeteridae (động vật) · Khối rắn hình thành trong ruột cá nhà táng, trôi dạt trên biển · Concretion formed in the sperm whale intestine, weathered at sea · Ground and macerated in ethanol (tincture), often aged; solvent extraction also used


Aroma

Good pieces: marine, warm skin, damp tobacco, wood, faintly faecal. Aged tincture: mineral, round, diffusive, not sweet. Young black pieces smell harsher, more faecal and marine.


Safety

Ambergris is not named in the index of the IFRA Standards, 51st Amendment. In the United States ambergris appears in the GRAS list at 21 CFR 182.50.

The sperm whale is listed in CITES Appendix I. Trade in ambergris is banned or restricted in some countries and allowed in others when the material is beach-found. Each lot should be checked against the law of the country of collection and of destination.

Store tincture dark, sealed and cool.


Usage guidelines

Note
Base
Commercial forms
Raw pieces, tincture
Role
Fixative, base diffusion
Replacements
Ambroxide and ambery molecules from sclareol
Storage
Dark, sealed, cool

Chemistry

Key constituents
Ambreinmajor, variable
Epicoprostanolmajor, variable
Ambroxide (oxidation product)trace
γ-Dihydroiononetrace

Origins

New Zealand · Australia · South Africa · Indian Ocean coasts


Notes

Ambergris forms in the sperm whale intestine, thought to build up around indigestible squid beaks. It is expelled into the sea, drifts for years and strands on shores. During drifting, light, seawater and air oxidise it; colour moves from black through grey to white. White, light pieces are graded highest.

Ambrein, a triterpene alcohol, is nearly odourless. The odour comes from oxidative breakdown products, among them ambroxide and dihydroionones. Epicoprostanol, a gut-derived sterol, is a marker of genuine ambergris.

For perfumery the pieces are ground and macerated in ethanol, usually aged for months. The tincture serves as a fixative and softens a structure. Supply is unpredictable and priced piece by piece.

The industry replaced ambergris with ambroxide and related molecules. Ambroxide is usually made from sclareol, taken from clary sage. The amber family in modern perfumery is therefore tied more to a plant than to a whale.

Ambergris is graded by colour, lightness, hardness and the smell released by a hot needle. Touched with a hot needle, a genuine piece melts into an oil and releases its characteristic smell. Laboratory chromatography can confirm ambrein and epicoprostanol.


Sources

  1. IFRA Standards, 51st Amendment: Index of IFRA Standards (notified 30 June 2023)
  2. US 21 CFR 182.50, GRAS natural extractives
  3. CITES Appendices I, II and III (current)
  4. Clarke R. The origin of ambergris. Latin American Journal of Aquatic Mammals 5(1) (2006) 7–21
  5. Rowland S.J., Sutton P.A. and co-workers, studies on ambergris chemistry (ambrein, epicoprostanol)
  6. PubChem compound record: Ambrein