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Black pepper CO2 extract

Tiêu đen CO2 extract

Piper nigrum

Pepper CO2 total, Pepper CO2 select, Pepper oleoresin (CO2)

Piperaceae · Quả khô (tiêu đen) · Dried unripe fruits (black peppercorns) · Supercritical or subcritical CO2 extraction


Aroma

Freshly ground pepper, dry wood, light citrus, a little resin and earth. The total extract carries clear heat; fuller and warmer than the oil, with rotundone's peppery wood.


Safety

Black pepper CO2 has no dedicated standard in the IFRA 51 index. Limonene and linalool are present and are EU-labelled allergens above threshold.

The total extract contains piperine, the pungent principle, which can feel hot on skin. Store dark, sealed and cool; monoterpenes oxidise easily.


Usage guidelines

Note
Top
Form
CO2 select, CO2 total
Role
Dry spicy top
Versus oil
Keeps piperine and woody notes
Storage
Dark, sealed, cool

Chemistry

Key constituents
β-Caryophyllenemajor
Limonenemajor
Sabinenepresent
α- and β-Pinenepresent
Rotundonetrace, odour-defining
Piperine (non-volatile)present in total extract

Origins

Vietnam · India · Indonesia · Brazil


Notes

Piper nigrum is a tropical vine native to the Malabar Coast of India. Black pepper is the fruit picked green and sun-dried; the skin darkens and wrinkles. White pepper is the ripe fruit with the skin removed.

Vietnam is the world's largest producer and exporter of pepper, with main growing areas in the Central Highlands and the Southeast. India, Indonesia, Brazil and Sri Lanka are other major sources.

CO2 extraction uses compressed carbon dioxide as the solvent. Under subcritical conditions CO2 takes mainly the volatile fraction, giving a product called a select extract. Under supercritical conditions it also takes lipids and non-volatiles, giving a total extract. On depressurisation the CO2 evaporates completely and leaves no solvent residue.

Rotundone, a sesquiterpene ketone, was identified as the key peppery-woody odorant, also found in Syrah grapes. It has a very low odour threshold. Piperine is non-volatile; it gives heat but no odour.

In perfumery black pepper CO2 serves spicy tops in woody, leather, masculine and rose fragrances. It adds dryness and warmth, unlike the fresh, sweet note of pink pepper.

Quality varies with region and drying. Unevenly dried or mouldy pepper carries a musty note and lowers extract quality.

Vietnamese pepper is commonly graded by bulk density in grams per litre.


Sources

  1. IFRA Standards, 51st Amendment: Index of IFRA Standards (notified 30 June 2023)
  2. Commission Regulation (EU) 2023/1545 amending Reg. 1223/2009 on labelling of fragrance allergens
  3. Wood C. et al. From wine to pepper: rotundone, an obscure sesquiterpene, is a potent spicy aroma compound. J. Agric. Food Chem. 56 (2008) 3738–3744
  4. International Pepper Community statistics
  5. PubChem compound record: Piperine
  6. The Good Scents Company Information System, material entries