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Cacao absolute

Ca cao absolute

Theobroma cacao

Cocoa absolute, Cocoa extract, Cacao CO2 extract

Malvaceae · Hạt ca cao đã lên men, sấy và rang · Fermented, dried and roasted cocoa beans · Solvent-extracted from roasted beans (CO2 extracts also produced)


Aroma

Dark chocolate, cocoa powder, roast, slightly earthy and woody. Dried-fruit and bitter facets. Not very sweet unless paired with vanilla.


Safety

Cacao absolute has no dedicated standard in the IFRA 51 index. Cocoa beans are a food; cocoa extracts are widely used in food flavours.

The absolute is dark brown and can discolour products. Store dark, sealed and cool.


Usage guidelines

Note
Base
Form
Absolute, CO2 extract, tincture
Role
Gourmand note, warm base
Colour
Dark brown
Storage
Dark, sealed, cool

Chemistry

Key constituents
Tetramethylpyrazinepresent
2,3,5-Trimethylpyrazinepresent
3-Methylbutanalpresent
Phenylacetaldehydetrace
Theobromine (non-volatile)present

Origins

Côte d'Ivoire · Ghana · Ecuador


Notes

Fresh cocoa beans barely smell of chocolate. The odour forms in three stages: fermentation with the pulp, drying and roasting. Fermentation creates precursors; roasting forms pyrazines and Strecker aldehydes through Maillard reactions.

The absolute is solvent-extracted from roasted, ground beans. Cocoa butter makes up about half the bean's weight and must be separated so the absolute dissolves in ethanol. CO2 extracts are also produced and are usually lighter in colour.

Cocoa odour has several families: pyrazines for roasted and nutty notes, 3-methylbutanal for malt, phenylacetaldehyde for a honeyed floral note. Theobromine is non-volatile and does not contribute odour directly.

In perfumery cacao absolute serves gourmand, oriental and woody fragrances. It pairs with patchouli, vanilla, tonka and orange. Its dark colour limits dosage in pale products.

Vietnam grows cacao in the Central Highlands and the Mekong Delta, but output is small next to West Africa. Côte d'Ivoire and Ghana supply most of the world's cocoa beans.

Cacao absolute is a near-black brown paste and can partly crystallise when cold. It is usually diluted in ethanol and left to settle for a few days. In soap and candles its dark colour affects the product colour. Many chocolate notes in modern perfume are built from synthetics such as pyrazines and vanillin, with cacao absolute adding natural depth.


Sources

  1. IFRA Standards, 51st Amendment: Index of IFRA Standards (notified 30 June 2023)
  2. Frauendorfer F., Schieberle P. Identification of the key aroma compounds in cocoa powder based on molecular sensory correlations. J. Agric. Food Chem. 54 (2006) 5521–5529
  3. ICCO, International Cocoa Organization statistics
  4. The Good Scents Company Information System, material entries