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Hexyl cinnamal

2-(phenylmethylidene)octanal

alpha-Hexylcinnamaldehyde, HCA

Aldehyde cinnamic · Cinnamic aldehyde · C₁₅H₂₀O

Chemical structure of Hexyl cinnamal
2D structure PubChem / NCI CIR

Chemical info

CAS number CAS
101-86-0
Molecular formula
C₁₅H₂₀O
Molecular weight
216.32 g/mol
Origin
Synthetic
Odor family
Floral
Note
Heart
Aroma
Soft jasmine-like floral, slightly waxy and herbal, round and mild.

History

alpha-hexylcinnamaldehyde is made by condensing benzaldehyde with octanal. It is one of the highest-volume synthetic fragrance materials.


In perfumery

A staple of budget jasmine and widely used in soap, detergent and cosmetics. Stable in alkaline media.


Connections

EvokesJasmine

Regulatory status

EU allergen
IFRA 51
Restricted by an IFRA Standard (entry "alpha-Hexyl cinnamic aldehyde"), current version issued at Amendment 49. Maximum levels differ across the 12 product categories.
EU CosReg
Annex III, entry 87 (labelled allergen).
EU allergen 2023/1545
One of the original 24 labelled fragrance allergens (Annex III, entry 87). Must be named on the label above 0.001% in leave-on and 0.01% in rinse-off products.

Sources

  1. NCI/CADD Chemical Identifier Resolver, CAS 101-86-0
  2. IFRA Standards Library, Amendments up to 51
  3. Regulation (EC) No 1223/2009, consolidated text of 18.05.2026, Annexes II and III